X-RAY AND MOLECULAR-STRUCTURE OF THE 1ST GERMACYCLOPENTENYL COMPOUND ETA-COORDINATED AND ETA-3-COORDINATED TO 2 COBALT CARBONYL FRAGMENTS

被引:2
|
作者
DUFOUR, P
MENU, MJ
DARTIGUENAVE, M
DARTIGUENAVE, Y
DUBAC, J
机构
[1] UNIV TOULOUSE 3,CHIM INORGAN LAB,205 ROUTE NARBONNE,F-31062 TOULOUSE,FRANCE
[2] UNIV TOULOUSE 3,ORGANOMET LAB,UA 477,F-31062 TOULOUSE,FRANCE
关键词
D O I
10.1021/om00052a001
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Thermal reaction of Co2(CO)8 with 1-phenyl-2,3,4,5-tetramethylgermole gave rise to the first germacyclopentenyl compound coordinated to two cobalt(I) carbonyl fragments, in an eta-1 mode to Co(CO)4 and in an eta-3 mode to Co(CO)3. The complex has been structurally characterized.
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页码:1645 / 1647
页数:3
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