CHARACTERIZATION OF POLYETHERPOLYURETHANE BY INVERSE GAS-CHROMATOGRAPHY

被引：2
|
作者：
FAROOQUE, AM [1 ]
DESHPANDE, DD [1 ]
机构：
[1] INDIAN INST TECHNOL,DEPT CHEM,BOMBAY 400076,INDIA
来源：
EUROPEAN POLYMER JOURNAL | 1992年 / 28卷 / 12期
关键词：
16;
D O I：
10.1016/0014-3057(92)90158-X
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Inverse gas chromatography has been used to characterize the interaction of polyetherpolyurethane with 17 solvents of various polarities at 100-150-degrees-C. The specific retention volume (V(g)0) measured for each probe was used to calculate various thermodynamic parameters and properties at infinite dilution, viz. chi, chi*, X12, DELTAH-1S, DELTAH-1infinity, DELTAG1infinity and TDELTAS1infinity. The dependencies on temperature and nature of the solvent are discussed. Also we have calculated the solubility parameter of the polymer using the method of Guillet and Dipaola-Baranyi at the above temperatures and also at 25-degrees-C.
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页码：1597 / 1600
页数：4
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