BIS(MU-BENZOATO-KAPPA-O-KAPPA-O'-BIS[(BENZOATO-KAPPA(2)O,O')(N,N-DIMETHYLFORMAMIDE-KAPPA-O)-DIOXOURANIUM(VI)]

被引：10
|
作者：
NAVAZA, A
IROULART, MG
NIERLICH, M
LANCE, M
VIGNER, J
机构：
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1993年 / 49卷
关键词：
D O I：
10.1107/S0108270193003518
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The action of dimethylformamide on diaqua(benzoato)chlorodioxouranium(VI), in the presence of beta-cyclodextrin, yields the title compound. The crystal structure of this new complex reveals that the linear uranyl is equatorially surrounded by five O atoms, one from a dmf molecule, two from a bidentate benzoate anion and one each from two separate bridging benzoate ligands, shared by the U atoms forming a neutral dimeric entity. The average U-O distance involving the bridging benzoates [2.31 (1) angstrom] is significantly shorter than that involving the other benzoates [2.44 (2) angstrom].
引用
收藏
页码：1767 / 1770
页数：4
相关论文
共 50 条
  • [1] Bis(mu(2)-benzoato-kappa(2) O:O ') bis[(benzoato-kappa O-2,O ')bis(4,4 '-bipyridine-kappa N)-cobalt (II)]-benzoic acid (1/6)
    Pena-Rodriguez, Rodolfo
    Maria Rivera, Jose
    Colorado-Peralta, Raul
    Maria Duarte-Hernandez, Angelica
    Flores-Parra, Angelina
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : M21 - +
  • [2] Tetrakis(mu-benzoato-O:O')bis(urea)-1 kappa O,2 kappa O-dicopper(II)
    Leban, I
    Grgurevic, N
    Sieler, J
    Segedin, P
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1997, 53 : 854 - 856
  • [3] Di-mu-benzoato-kappa O-3, O':O;kappa O-3:O,O'-bis-[aqua(nitrato-kappa O) (1,10-phenanthroline-kappa N-2,N')lead(II)]
    Cheng, Yuanzheng
    Yan, Fang
    Shi, Weiwei
    Zhang, Liping
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M528 - +
  • [4] CATENA-POLY[(AQUA(CYANOACETATO-KAPPA-O)(N,N-DIMETHYLFORMAMIDE-KAPPA-O)NEODYMIUM)-DI-MU-CYANOACETATO-KAPPA-O, KAPPA-O'-KAPPA-O'] MONOHYDRATE
    STARYNOWICZ, P
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1993, 49 : 1621 - 1623
  • [5] Bis(mu-diisopropylhydoxylaminato)-kappa O-2:N; kappa O-2:O-bis[(diisopropylhydoxylaminato-kappa O) beryllium]
    Berger, Raphael Johann Friedrich
    Jana, Surajit
    Monkowius, Uwe
    Mitzel, Norbert Werner
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M1463 - +
  • [6] Crystal structure of bis(mu(2)-methoxy-kappa O:kappa O)hexamethylbis(mu(2)-triphenylacetato-kappa O:kappa O ')bis(mu(2)-triphenylacetato-kappa O-2,O ':kappa O)dialuminium-dilanthanum toluene tetrasolvate
    Vinogradov, Alexander A.
    Roitershtein, Dmitrii M.
    Minyaev, Mikhail E.
    Lyssenko, Konstantin A.
    Nifant'ev, Ilya E.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2018, 74 : 1790 - +
  • [7] catena-Poly[[[diaqua[3-(pyridin-4-yl)benzoato-kappa O-2,O ']gadolinium(III)]-bis[mu-3-(pyridin-4-yl)benzoato-kappa O-2:O ']] monohydrate]
    Li, Dong-Ying
    Li, Guo-Ting
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M928 - +
  • [8] (mu-Acetato-kappa O-2:O')[mu-2,6-bis({bis[(pyridin-2-yl-kappa N)methyl]amino-kappa N}methyl)-4-methylphenolato-kappa O-2:O](methanol-kappa O)dizinc bis(perchlorate)
    Das, Biswanath
    Haukka, Matti
    Nordlander, Ebbe
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : M120 - +
  • [9] Bis(mu-4-formylbenzoato-kappa(2) O:O ') bis[(4-formylbenzoato-kappa(2) O, O ') bis(isonicotin-amide-kappa N-1) copper(II)]
    Sertcelik, Mustafa
    Delibas, Nagihan Caylak
    Necefoglu, Hacali
    Hokelek, Tuncer
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : M290 - +
  • [10] A second triclinic polymorph of bis(mu-N-nitroso-N-phenylhydroxylaminato)-kappa O-3,O ':O ';kappa O-3 ':O,O '-bis[(N-nitroso-N-phenylhydroxylaminato-kappa O-2,O ')lead(II)]
    Najafi, Ezzatollah
    Amini, Mostafa M.
    Ng, Seik Weng
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M791 - +
12345