STUDIES ON THERMO KINETIC METHOD (I) DETERMINATION OF REACTION RATE CONSTANTS AND ACTIVATION ENERGIES BY CALORIMETRY

被引：15

作者：

Xie Changli ^{[1
]}

Xu Quiduan ^{[1
]}

Qu Songsheng ^{[1
]}

Owusu, Richard K. ^{[2
]}

机构：

[1] Wuhan Univ, Dept Chem, Wuhan, Peoples R China

[2] Univ London, Royal Hollway Coll, Dept Chem, London WC1E 7HU, England

来源：

ACTA PHYSICO-CHIMICA SINICA | 1986年 / 2卷 / 04期

关键词：

D O I：

10.3866/PKU.WHXB19860416

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The esterification rate constants of the acetic acid with the methanol and ethanol at various temperatures were determined by the flow rnicrocalorimetry, while with the help of Arrhenius relation the activation energies of these reactions were determined. In order to check the reliability of method, the hydrolysis (reversal reaction of esterification) rate constants of methyl and ethyl acetates were determined, the results of experiments are consistent with results of calculation from the data of esterification experiments.

引用

页码：363 / 370

页数：8