REACTION OF STEROIDAL EPOXIDES WITH THIOGLYCOLIC ACID

被引:0
|
作者
SHAFIULLAH [1 ]
JAMALUDDIN, M [1 ]
SIDDIQUI, IH [1 ]
OGURA, H [1 ]
TAKAYANAGI, H [1 ]
机构
[1] KITASATO UNIV,SCH PHARMACEUT SCI,MINATO KU,TOKYO 108,JAPAN
来源
INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY | 1991年 / 30卷 / 07期
关键词
D O I
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中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Reaction of 5,6-alpha-epoxy-5-alpha-cholestane (1), its 3-beta-chloro (2), 3-beta-acetoxy (3) and 3-beta-hydroxy (4) analogues with thioglycolic acid affords hydroxy formates (5-8) along with the diols (9-12). The structures of these products have been established on the basis of their analytical and spectral data. The structure of compound 6 was further supported by its X-ray analysis.
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页码:700 / 701
页数:2
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