CO(SALEN) CATALYZED OXIDATION OF 2,4,6-TRISUBSTITUTED ANILINES WITH TERT-BUTYLHYDROPEROXIDE

被引：16
|
作者：
NISHINAGA, A [1 ]
FORSTER, S [1 ]
EICHHORN, E [1 ]
SPEISER, B [1 ]
RIEKER, A [1 ]
机构：
[1] UNIV TUBINGEN,INST ORGAN CHEM,W-7400 TUBINGEN 1,GERMANY
来源：
TETRAHEDRON LETTERS | 1992年 / 33卷 / 31期
关键词：
D O I：
10.1016/S0040-4039(00)60100-4
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Co(salen) catalyzed oxidation of 2,4,6-trisubstituted (preferentially 2,6-di-tert-butylated) anilines with tert-butylhydroperoxide gives 4-tert-butylperoxy-2,5-cyclohexadien-1-imine and nitrobenzene derivatives. The relative ratio of the products depends on the nature of the substituents in the substrate.
引用
收藏
页码：4425 / 4428
页数：4
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