PROBING INTERMOLECULAR DYNAMICS IN LIQUIDS BY FEMTOSECOND OPTICAL KERR-EFFECT SPECTROSCOPY - EFFECTS OF MOLECULAR SYMMETRY

被引：54
|
作者：
DEUEL, HP
CONG, PJ
SIMON, JD
机构：
[1] UNIV CALIF SAN DIEGO,DEPT CHEM,LA JOLLA,CA 92093
[2] UNIV CALIF SAN DIEGO,INST NONLINEAR SCI,LA JOLLA,CA 92093
来源：
JOURNAL OF PHYSICAL CHEMISTRY | 1994年 / 98卷 / 48期
关键词：
D O I：
10.1021/j100099a024
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Intermolecular dynamics in a series of nitriles and substituted methanes are investigated using optical-heterodyne-detected Raman-induced Kerr effect spectroscopy (OHD-RIKES) with similar to 30 fs laser pulses. The results obtained unequivocally establish a correlation between molecular symmetry and the ratio of intermolecular vs intramolecular contribution to the Kerr signal. Quantitative connections between molecular anisotropy and optical Kerr measurements are discussed. The utility of low-frequency spectral densities measured by OHD-RIKES in relation to studies on dynamics in liquids is addressed.
引用
收藏
页码：12600 / 12608
页数：9
相关论文
共 50 条
  • [1] PROBING INTERMOLECULAR DYNAMICS IN LIQUIDS BY FEMTOSECOND OPTICAL-KERR-EFFECT SPECTROSCOPY - EFFECTS OF MOLECULAR SYMMETRY
    DEUEL, HP
    CONG, P
    SIMON, JD
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1994, 208 : 372 - PHYS
  • [2] Femtosecond selective optical Kerr-effect spectroscopy: Molecular dynamics study of chloroform
    Shmelev, A. G.
    Nikiforov, V. G.
    Safiullin, G. M.
    Lobkov, V. S.
    Samartsev, V. V.
    LASER PHYSICS, 2010, 20 (12) : 2015 - 2020
  • [3] Probing the intermolecular dynamics of liquids by femtosecond spectroscopy
    Simon, JD
    Cong, PJ
    Chang, YJ
    ULTRAFAST PROCESSES IN SPECTROSCOPY, 1996, : 79 - 83
  • [4] Dynamics of molecular liquids studied by femtosecond optical Kerr effect
    Wiewiór, P
    Radzewicz, C
    OPTICA APPLICATA, 2000, 30 (01) : 103 - 120
  • [5] Femtosecond pulse shaping enables detection of optical Kerr-effect (OKE) dynamics for molecular imaging
    Robles, Francisco E. (francisco.robles@duke.edu), 1600, Optical Society of America (OSA) (39):
  • [6] Femtosecond pulse shaping enables detection of optical Kerr-effect (OKE) dynamics for molecular imaging
    Robles, Francisco E.
    Fischer, Martin C.
    Warren, Warren S.
    OPTICS LETTERS, 2014, 39 (16) : 4788 - 4791
  • [7] Femtosecond pulse shaping enables detection of optical Kerr-effect (OKE) dynamics for molecular imaging
    Robles, F.E. (francisco.robles@duke.edu), 1600, Optical Society of America (OSA) (39):
  • [8] Structure and intermolecular dynamics of liquids: Femtosecond optical Kerr effect measurements in nonpolar fluorinated benzenes
    Neelakandan, M
    Pant, D
    Quitevis, EL
    JOURNAL OF PHYSICAL CHEMISTRY A, 1997, 101 (16): : 2936 - 2945
  • [9] FEMTOSECOND OPTICAL KERR-EFFECT STUDIES OF WATER
    PALESE, S
    SCHILLING, L
    MILLER, RJD
    STAVER, PR
    LOTSHAW, WT
    JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (25): : 6308 - 6316
  • [10] Exponential intermolecular dynamics in optical Kerr effect spectroscopy of small-molecule liquids
    Loughnane, BJ
    Scodinu, A
    Farrer, RA
    Fourkas, JT
    Mohanty, U
    JOURNAL OF CHEMICAL PHYSICS, 1999, 111 (06): : 2686 - 2694
12345