KINETICS OF OXIDATION OF PARA-SUBSTITUTED AND META-SUBSTITUTED BENZALDEHYDES BY PYRIDINIUM CHLOROCHROMATE

被引：0

作者：

PILLAY, MK ^{[1
]}

JAMEEL, AA ^{[1
]}

机构：

[1] JAMAL MOHAMED COLL, DEPT CHEM, Tiruchirappalli 620020, INDIA

来源：

INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 1992年 / 31卷 / 01期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The oxidation of para- and meta-substituted benzaldehydes by pyridinium chlorochromate (PCC) is first order each in substrate, [PCC] and [H+]. Electron-releasing substituents retard and the electron-withdrawing groups enhance the rate. Addition of monomer to the reaction mixture gives a polymer. Activation parameters have been computed and a suitable mechanism has been postulated.

引用

页码：46 / 48

页数：3

共 50 条

[1] KINETICS OF OXIDATION OF SOME META-SUBSTITUTED AND PARA-SUBSTITUTED DIMETHYLANILINES WITH LEAD-TETRAACETATE
GALLIANI, G
RINDONE, B
BELTRAME, PL
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1976, (15): : 1803 - 1805
[2] KINETICS OF THE DECOMPOSITION OF ORTHO-SUBSTITUTED, META-SUBSTITUTED, AND PARA-SUBSTITUTED BENZOYLAZIDES
KOSOLAPOV, VT
ZLOBIN, VA
IOGANOV, KM
TARASOV, AK
KINETICS AND CATALYSIS, 1983, 24 (03) : 613 - 615
[3] KINETICS OF THALLIUM(III) OXIDATION OF PARA-SUBSTITUTED AND META-SUBSTITUTED ALPHA-PHENYLETHYL ALCOHOLS
SRINIVAS.VS
VENKATAS.N
INDIAN JOURNAL OF CHEMISTRY, 1970, 8 (09): : 849 - &
[4] Kinetics and mechanism of oxidation of substituted benzaldehydes by 4-(dimethylamino)pyridinium chlorochromate
Krishnasamy, K.
Devanathan, D.
Dharmaraja, J.
TRANSITION METAL CHEMISTRY, 2007, 32 (07) : 922 - 926
[5] Kinetics and mechanism of oxidation of substituted benzaldehydes by 4-(dimethylamino)pyridinium chlorochromate
K. Krishnasamy
D. Devanathan
J. Dharmaraja
Transition Metal Chemistry, 2007, 32 : 922 - 926
[6] KINETICS OF OXIDATION OF SUBSTITUTED BENZALDEHYDES BY QUINOLINIUM CHLOROCHROMATE
ELANGO, KP
KARUNAKARAN, K
ASIAN JOURNAL OF CHEMISTRY, 1995, 7 (04) : 798 - 800
[7] KINETICS OF REACTION OF META-SUBSTITUTED AND PARA-SUBSTITUTED BENZENEDIAZONIUM IONS WITH OH-IONS
BERANEK, V
STERBA, V
VALTER, K
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1973, 38 (01) : 257 - 260
[8] KINETICS OF OXIDATION OF PARA-SUBSTITUTED PHENYL METHYL SULFIDES BY PYRIDINIUM CHLOROCHROMATE IN DIPOLAR PROTIC AND APROTIC-SOLVENTS
RAJASEKARAN, K
BASKARAN, T
GNANASEKARAN, C
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1984, (07): : 1183 - 1186
[9] PHOTOCHEMISTRY OF META-SUBSTITUTED AND PARA-SUBSTITUTED AROMATIC POLYCARBONYL COMPOUNDS
ITO, Y
KAWATSUKI, N
GIRI, BP
YOSHIDA, M
MATSUURA, T
JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (16): : 2893 - 2904
[10] KINETICS OF THE INTERACTION OF ORTHO-SUBSTITUTED, META-SUBSTITUTED, AND PARA-SUBSTITUTED BENZOYL CHLORIDES WITH THE AZIDE ION
KOSOLAPOV, VT
ZLOBIN, VA
IOGANOV, KM
TARASOV, AK
KINETICS AND CATALYSIS, 1981, 22 (02) : 235 - 238

← 1 2 3 4 5 →