FACTORS INFLUENCING THE STEREOSELECTIVITY IN THE CYCLOADDITION OF IMINO-DIENOPHILES DERIVED FROM AMINO ETHERS, AMINO-ALCOHOLS, AND AMINO-ACID ESTERS

被引：33
|
作者：
DEVINE, PN [1 ]
REILLY, M [1 ]
OH, T [1 ]
机构：
[1] SUNY,DEPT CHEM,BINGHAMTON,NY 13902
来源：
TETRAHEDRON LETTERS | 1993年 / 34卷 / 37期
关键词：
D O I：
10.1016/S0040-4039(00)73790-7
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Imino dienophiles derived from amino ethers, amino alcohols and amino esters undergo Lewis acid promoted cycloaddition with Danishefsky's diene. Cyclic chelation between the imine and oxygen atom increases the stereoselectivity of the reaction.
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页码：5827 / 5830
页数：4
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