CHEMISTRY OF GALLIUM .3. SYNTHESIS AND STRUCTURE OF A TETRAAMINO-SUBSTITUTED DIGALLANE

被引：0
|
作者：
LINTI, G
FREY, R
SCHMIDT, M
机构：
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1994年 / 49卷 / 07期
关键词：
GALLIUM AMIDES; DIGALLANE; METAL(II) AMIDE;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Dehalogenation of tmp(2)GaCl (tmp = 2,2,6,6-tetramethyl piperidino group) with sodium/ potassium alloy leads to the digallane (tmp)(2)Ga-Ga(tmp)(2) as a pale yellow solid. Alternatively this digallane is prepared in good yields by reaction of four equivalents of tmpLi with Ga2Cl4.2 dioxane. Ga-2(tmp)(4) is characterized by MS, NMR (H-1 and C-13) and X ray structure determination. The gallium-gallium bond length is 252.5(1) pm and its two GaN2 units are twisted by 31 degrees against each other.
引用
收藏
页码：958 / 962
页数：5
相关论文
共 50 条
  • [1] Synthesis of diamino-substituted and tetraamino-substituted dibenzo-18-crown-6 esters and certain nitrous heterocycles based on them
    Ovchinnikova, IG
    Fedorova, OV
    Rusinov, GL
    ZHURNAL ORGANICHESKOI KHIMII, 1999, 35 (07): : 1106 - 1109
  • [2] SYNTHESIS AND MOLECULAR-STRUCTURE OF TETRAKIS[BIS(TRIMETHYLSILYL)METHYL]DIGALLANE(4) WITH GALLIUM-GALLIUM BONDS
    UHL, W
    LAYH, M
    HILDENBRAND, T
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 364 (03) : 289 - 300
  • [3] CHEMISTRY OF CHELOCARDIN .3. STRUCTURE AND SYNTHESIS OF ISOCHELOCARDIN
    BERNSTEIN, E
    CHU, DTW
    HUCKIN, SN
    GARMAISE, DL
    EGAN, RS
    PERUN, TJ
    ROSENBROOK, W
    CARNEY, RE
    JOURNAL OF ORGANIC CHEMISTRY, 1978, 43 (14): : 2855 - 2860
  • [4] On the chemistry of gallium .8. Synthesis and structure of [tris(trimethylsilyl)silyl]-substituted gallanes and gallates
    Linti, G
    Frey, R
    Kostler, W
    Urban, H
    CHEMISCHE BERICHTE, 1996, 129 (05) : 561 - 569
  • [5] CONTRIBUTION TO THE CHEMISTRY OF GALLIUM .3. SULPHOGALLATES OF THE ALKALINE METALS
    IVANOVEMIN, BN
    RABOVIK, JI
    ZHURNAL OBSHCHEI KHIMII, 1947, 17 (07): : 1247 - 1252
  • [6] CHEMISTRY OF PONGAMOL .3. SYNTHESIS
    MUKERJEE, SK
    SESHADRI, TR
    JOURNAL OF THE CHEMICAL SOCIETY, 1955, : 2048 - 2049
  • [7] Synthesis, Structure and Chemistry of Mono- and Digallane Complexes Supported by N,O-Ketimine Ligand
    Bakthavachalam, Kirubakaran
    Yuvaraj, Kuppusamy
    Raghavendra, Beesam
    Dorcet, Vincent
    Roisnel, Thierry
    Rit, Arnab
    Ghosh, Sundargopal
    CHEMISTRYSELECT, 2017, 2 (24): : 7450 - 7454
  • [8] CHEMISTRY OF PROXIMAL PI-BOND SYSTEMS .3. SYNTHESIS OF SUBSTITUTED BENZOPOLYCYCLIC HYDROCARBONS
    BUTLER, DN
    SNOW, RA
    CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1975, 53 (02): : 256 - 262
  • [9] CHEMISTRY OF PSEUDOURIDINE .3. STRUCTURE OF A ISOMERS
    CHAMBERS, RW
    KURKOV, V
    BIOCHEMISTRY, 1964, 3 (03) : 326 - &
  • [10] CHEMISTRY OF POLYTHIENYLS .3. SYNTHESIS OF TERTHIENYLS
    KOOREMAN, HJ
    WYNBERG, H
    RECUEIL DES TRAVAUX CHIMIQUES DES PAYS-BAS, 1967, 86 (01): : 37 - &
12345