RADICAL COPOLYMERIZATION OF LIPOAMIDE WITH VINYL MONOMERS

被引：30
|
作者：
SUZUKI, T [1 ]
NAMBU, Y [1 ]
ENDO, T [1 ]
机构：
[1] TOKYO INST TECHNOL,RESOURCES UTILIZAT RES LAB,MIDORI KU,YOKOHAMA,KANAGAWA 227,JAPAN
来源：
MACROMOLECULES | 1990年 / 23卷 / 06期
关键词：
D O I：
10.1021/ma00208a004
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Lipoamide, which is a five-membered cyclic disulfide, was copolymerized with some vinyl monomers (styrene, vinyl acetate, acrylonitrile, and methyl acrylate) by 2,2'-azobis(isobutyronitrile) as a radical initiator at 82°C for 2 h in benzene to give copolymers with sulfide linkages in the main chain and various functional groups as pendants in good yield. The copolymerization might proceed by chain-transfer-type attacking of the propagating vinyl polymer radical at the S-S bond of lipoamide. © 1990, American Chemical Society. All rights reserved.
引用
收藏
页码：1579 / 1582
页数：4
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