Molecule Matters N-Heterocyclic Carbenes - The Stable Form of R2C

被引：0

作者：

Elias, Anil J. ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Delhi 110016, India

来源：

RESONANCE-JOURNAL OF SCIENCE EDUCATION | 2008年 / 13卷 / 05期

关键词：

Stable carbene; olefin metathesis; Fischer; Schrock; Grubbs; heterocyclic;

D O I：

10.1007/s12045-008-0052-7

中图分类号：

G40 [教育学];

学科分类号：

040101 ; 120403 ;

摘要：

Divalent carbon compounds which were once considered as highly reactive organic intermediates have been tamed by the modern day synthetic chemist in the form of N-heterocyclic carbenes. The land marks in the history of development of these compounds and their applications as ligands in the Nobel Prize winning work on olefinmetathesis catalysts are described.

引用

页码：456 / 467

页数：12

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