Crystal structure of bis(isonicotinamide-kappa N-1)bis(thiocyanato-kappa N)zinc

被引：4
|
作者：
Neumann, Tristan [1 ]
Jess, Inke [1 ]
Naether, Christian [1 ]
机构：
[1] Univ Kiel, Inst Anorgan Chem, Max Eyth Str 2, D-24118 Kiel, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2016年 / 72卷
关键词：
crystal structure; discrete complex; zinc thiocyanate; isonicotinamide; hydrogen bonding;
D O I：
10.1107/S2056989016008963
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The asymmetric unit of the title complex, [Zn(SCN)(2)(C6H6N2O)(2)], consists of one Zn2+ cation located on a twofold rotation axis, as well as of one thiocyanate anion and one neutral isonicotinamide ligand, both occupying general positions. The Zn2+ cation is tetrahedrally coordinated into a discrete complex by the N atoms of two symmetry-related thiocyanate anions and by the pyridine N atoms of two isonicotinamide ligands. The complexes are linked by intermolecular C-H center dot center dot center dot O and N-H center dot center dot center dot O, and weak intermolecular N-H center dot center dot center dot S hydrogen-bonding interactions into a three-dimensional network.
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收藏
页码：922 / +
页数：7
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