STATISTICAL-THEORY OF THE ELASTIC-CONSTANTS OF NEMATIC LIQUID-CRYSTALS

被引:149
作者
PONIEWIERSKI, A
STECKI, J
机构
[1] Laboratory No. 3 Institute of Physical Chemistry, Polish Academy of Sciences, Warsaw
关键词
D O I
10.1080/00268977900102951
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A statistical mechanical theory of the Frank elastic constants is formulated. The free energy functional is constructed for the deformed sample and the free energy density is defined for the case of small spatial gradients. The Frank constants are expressed in terms of the direct correlation function c(l, 2) and the orientational single particle distribution function. For the example of Onsager spherocylinders three constants K1, K2 and K3 are calculated. The results of these calculations are similar to those given by Priest and by Straley. © 1979 Taylor & Francis Ltd.
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页码:1931 / 1940
页数:10
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