REVERSIBLE COVALENT ATTACHMENT OF C-60 TO A FURAN-FUNCTIONALIZED RESIN

被引：25
|
作者：
NIE, B [1 ]
HASAN, K [1 ]
GREAVES, MD [1 ]
ROTELLO, VM [1 ]
机构：
[1] UNIV MASSACHUSETTS,DEPT CHEM,AMHERST,MA 01003
来源：
TETRAHEDRON LETTERS | 1995年 / 36卷 / 21期
基金：
美国国家科学基金会;
关键词：
D O I：
10.1016/0040-4039(95)00578-Z
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Reaction of Merrifield's peptide resin with the sodium anion of furfuryl alcohol provides a furan-functionalized polymer resin. This polymer reacts rapidly with C-60 to provide a fullerene-substituted polymer, presumably via Diels-Alder reaction, with the furan as diene and the fullerene as dienophile. This resin is greater than two-fold more efficient in C-60 uptake, and provides a 66% increase in C-60 release upon heating, compared with the previously reported cyclopentadiene-functionalized resin.
引用
收藏
页码：3617 / 3618
页数：2
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