CATION-RADICAL MECHANISMS OF CATALYTIC HYDROCARBON CONVERSIONS - ISOMERIZATION OF ALKENES

被引：0

作者：

VISHNETSKAYA, MV

ROMANOVSKII, BV

机构：

[1] M.V. Lomonosov Moscow State Univ, Moscow, Russia

来源：

PETROLEUM CHEMISTRY | 1993年 / 33卷 / 04期

关键词：

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An examination has been made of single-electron transfer from a substrate molecule to the catalyst and the formation of a cation-radical as the first stage of alkene isomerization. Within the framework of this model, the stereospecificity of the reaction and the formation of cis-isomers as primary isomerization products are explained. as well as data on deuterated exchange.

引用

页码：299 / 302

页数：4

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