Bis[mu-N-(tert-butyldimethylsilyl)quinolin-8-aminato-1:2 kappa(2)N1,N-8:N-8](N,N,N',N'-tetramethylethane-1,2-diamine-1 kappa N-2,N')lithiumsodium

被引：2

作者：

Chen, Juan ^{[1
]}

Yuan, Li ^{[2
]}

机构：

[1] Taiyuan Teachers Coll, Dept Chem, Taiyuan 030031, Shanxi, Peoples R China

[2] Sanxi Entry Exit Inspect & Quarantine Bur, Tech Ctr, Taiyuan 030024, Shanxi, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷

关键词：

D O I：

10.1107/S160053681204576X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the heterometallic title bulky amido complex, [LiNa(C15H21N2Si)(2)(C6H16N2)], both alkali metal ions are four-coordinated with distorted tetrahedral geometries. The Li+ ion is N, N'-chelated by the N-silylated amido ligand, with Li-N = 2.015 (5) and 2.074 (5) angstrom. The two amido ligands are arranged cis to each other. The molecule exhibits a twofold rotational symmetry operation along the Li-Na axis. The Na + ion is coordinated by two N atoms from the tetramethylethylenediamine ligand [Na-N = 2.553 (4) angstrom] and shares two amido N atoms from the N-silylated amido ligands with the Li + ion. Although the crystal structure contains voids with an approximate volume of 50 angstrom(3) there is no inclusion of solvent molecules.

引用

页码：M1474 / +

页数：9

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