ELECTRON-TRANSFER PROCESSES .51. EFFECTS OF IODIDE-ION AND AMINES ON THE FREE-RADICAL ALKYLATION OF 1,4-ENEDIONES BY ALKYLMERCURY HALIDES

被引：9
|
作者：
RUSSELL, GA
KIM, BH
机构：
[1] Department of Chemistry, Iowa State University, Ames
来源：
TETRAHEDRON LETTERS | 1990年 / 31卷 / 44期
基金：
美国国家科学基金会;
关键词：
D O I：
10.1016/S0040-4039(00)97040-0
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Iodide ion promotes the photostimulated reductive alkylation of α,{amalgamation}-unsaturated ketones by electron transfer from RHgl2- to the adduct enolyl radicals. Amines such as Dabco can promote oxidative alkylation by removal of a proton from the adduct radicals. © 1990.
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页码：6273 / 6276
页数：4
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