On the submillimetre wave refraction of liquids

被引:16
作者
Chamberlain, J. [1 ]
机构
[1] Natl Phys Lab, Div Elect Sci, Teddington TW11 0LW, Middx, England
关键词
D O I
10.1016/0009-2614(65)80012-4
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
It is shown that the refractive index associated with a heavily damped Lorentzian oscillator of low resonant frequency is radically different in spectral form from that found for the more familiar lightly damped oscillator. The complex refraction spectrum of a crude model consisting of three such overlapping oscillators of equal strengths and linearly spaced resonant frequencies shows a striking qualitative resemblance to the observed submillimetre spectra of liquids. The consistency of the agreement for both refraction and absorption supports the suggestion of Hill that a more sophisticated model involving the superposition of a range of heavily damped resonances is applicable to these liquid spectra.
引用
收藏
页码:464 / 468
页数:5
相关论文
共 9 条
[1]   SUBMILLIMETRE DISPERSION OF LIQUID TETRABROMOETHANE [J].
CHAMBERL.JE ;
COSTLEY, AE ;
GEBBIE, HA .
SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY, 1967, A 23 (08) :2255-&
[2]   Millimetre-wave Fourier transform spectroscopy for studies of the liquid state [J].
Chamberlain, J. E. ;
Gebbie, H. A. ;
Pardoe, G. W. F. ;
Davies, Mansel .
CHEMICAL PHYSICS LETTERS, 1968, 1 (11) :523-525
[3]   SUB-MILLIMETRE WAVE SPECTRA OF POLAR LIQUIDS [J].
CHANTRY, GW ;
GEBBIE, HA .
NATURE, 1965, 208 (5008) :378-&
[4]   SUB-MILLIMETRE WAVE SPECTRA OF NON-POLAR LIQUIDS AND CRYSTALS [J].
CHANTRY, GW ;
GEBBIE, HA ;
LASSIER, B ;
WYLLIE, G .
NATURE, 1967, 214 (5084) :163-&
[5]   CHARACTER OF ABSORPTION IN FAR INFRA-RED BY POLAR MOLECULES IN LIQUID STATE [J].
DAVIES, M ;
PARDOE, GWF ;
CHAMBERLAIN, JE ;
GEBBIE, HA .
TRANSACTIONS OF THE FARADAY SOCIETY, 1968, 64 (544P) :847-+
[6]   Optical absorption and dielectric loss due to resonance in liquids [J].
Hill, Nora E. .
CHEMICAL PHYSICS LETTERS, 1968, 2 (01) :5-7
[7]   Optical dispersion [J].
Korff, SA ;
Breit, G .
REVIEWS OF MODERN PHYSICS, 1932, 4 (03) :0471-0503
[8]   Rotation-translation spectra of polar molecules in liquids [J].
Kroon, S. G. ;
Van der Elsken, J. .
CHEMICAL PHYSICS LETTERS, 1967, 1 (07) :285-288
[9]  
LEROY Y, 1966, CR ACAD SCI B PHYS, V262, P1391