RADICAL TELOMERIZATION OF 3,3,3-TRIFLUOROPROPENE WITH 2-METHYL-1,3-DIOXOLANE

被引：0
|
作者：
TERENTEV, AB
PASTUSHENKO, EV
KRUGLOV, DE
RYABININA, TA
机构：
来源：
BULLETIN OF THE RUSSIAN ACADEMY OF SCIENCES-DIVISION OF CHEMICAL SCIENCE | 1992年 / 41卷 / 12期
关键词：
RADICALS; ADDITION; DIOXOLANE; TELOMERS; TELOMERIZATION; KINETICS;
D O I：
10.1007/BF01150746
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The telomerization of 3,3,3-trifluoropropene with 2-methyl-1,3-dioxolane gives predominantly cyclic telomers as shown by C-13 NMR and gas chromatography-mass spectrometry. This reaction is accompanied by the rearrangement of transient free radical intermediates via 1,5-H-migration.
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页码：2197 / 2200
页数：4
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