Anomalous heat capacity of spherical clusters of atoms

被引：24

作者：

Burton, J. J. ^{[1
,2
]}

机构：

[1] Univ Illinois, Dept Phys, Urbana, IL 61801 USA

[2] Univ Illinois, Mat Res Lab, Urbana, IL 61801 USA

来源：

CHEMICAL PHYSICS LETTERS | 1969年 / 3卷 / 08期

关键词：

D O I：

10.1016/0009-2614(69)85118-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The heat capacities of small spherical clusters of atoms arc calculated in the harmonic a for clusters of up to 55 atoms. The heat capacities do not take the expected form C(T) = AT(3) + BT2. The heat capacity per atom is not monotonic in the number of atoms.

引用

页码：594 / 596

页数：3

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