5-COORDINATE RHODIUM(III) COMPLEXES CONTAINING THE NOVEL TEF3 LIGAND

被引：14

作者：

EBSWORTH, EAV

HOLLOWAY, JH

WATSON, PG

机构：

[1] UNIV LEICESTER,DEPT CHEM,LEICESTER LE1 7RH,ENGLAND

[2] UNIV EDINBURGH,DEPT CHEM,EDINBURGH EH9 3JJ,MIDLOTHIAN,SCOTLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 20期

关键词：

D O I：

10.1039/c39910001443

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tellurium tetrafluoride reacts at 195 K in CD2Cl2 with Rh(CO)X(PEt3)2 [X = Cl, Br, NCS, NCO] to give the novel complexes [Rh(CO)X(PEt3)2(TeF3)+][TeF5-], which have been characterised by F-19, P-31 and C-13 NMR spectroscopy; for X = Cl, Br and NCS the complexes are stable at ambient temperature but for X = NCO decomposition occurs at 215 K.

引用

页码：1443 / 1444

页数：2

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