SQUARE-WAVE VOLTAMMETRIC DETERMINATION OF COPPER(II) WITH A NAFION DIMETHYLGLYOXIME MERCURY-FILM ELECTRODE

被引:21
|
作者
ZEN, JM
CHI, NY
HSU, FS
CHUNG, MJ
机构
关键词
SQUARE-WAVE ANODIC STRIPPING VOLTAMMETRY; MERCURY-FILM ELECTRODE; NAFION; COPPER DETERMINATION; DIMETHYLGLYOXIME;
D O I
10.1039/an9952000511
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The use of a dimethylglyoxime modified Nafion-coated mercury-film electrode in square-wave anodic stripping voltammetry for the determination of copper(II) is described. Compared with a Nafion-coated mercury-film electrode, this modified electrode showed improved resistance to interferences from surface-active compounds and much better selectivity. In addition, detection can be achieved without deoxygenation and the electrode can be easily renewed.
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页码:511 / 515
页数:5
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