TRANSFORMATIONS OF ALPHA-PINENE AND BETA-PINENE OXIDES OVER BINARY OXIDE CATALYSTS OF ALUMINA RARE-EARTH-OXIDES .2.

被引:14
|
作者
JAYASREE, J [1 ]
NARAYANAN, CS [1 ]
机构
[1] CSIR, REG RES LAB, THIRUVANANTHAPURAM 695019, KERALA, INDIA
关键词
D O I
10.1246/bcsj.68.89
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The catalytic activity of binary oxides of Al2O3-Eu2O3, Al2O3-Sm2O3, Al2O3-Nd2O3, Al2O3-Pr6O11, and Al2O3-Y2O3 were checked in the transformations of alpha and beta-pinene oxides. Al2O3-Eu2O3 and Al2O3-Nd2O3 are found to be best catalysts for alpha-pinene oxide isomeriztion. Among the oxiranes, alpha-pinene oxide showed more activity mainly yielding 2,2,3-trimethyl cyclopentene-1-acetaldehyde. beta-pinene oxide produced trans-myrtanal and myrtanol.
引用
收藏
页码:89 / 94
页数:6
相关论文
共 47 条