CHEMICAL AND ELECTROCHEMICAL STUDIES ON METAL-CARBONYL COBALTOCENE SYSTEMS

被引：6
|
作者：
PAMPALONI, G [1 ]
KOELLE, U [1 ]
机构：
[1] RHEIN WESTFAL TH AACHEN,INST ANORGAN CHEM,D-52056 AACHEN,GERMANY
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 481卷 / 01期
关键词：
COBALT; MANGANESE; VANADIUM; ELECTROCHEMISTRY; CARBONYL; COBALTOCENE;
D O I：
10.1016/0022-328X(94)85002-X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The chemical and electrochemical behaviour of compounds of the type [Co(C(5)R(5))(2)][M(CO)(n)] (R = H, Me; M = Mn; n = 5; R = H; M = Co, n = 4; M = V; n = 6) was studied. A relationship between the chemical behaviour and the redox potentials of the components of the complexes was obtained. The reduction of [MnX(CO)(5)] (X = Cl, Br or I) by cobaltocene in different solvents was studied by both chemical and electrochemical methods.
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页码：1 / 6
页数：6
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