INFLUENCE OF THE AMBIENT MEDIUM ON THE DISJOINING PRESSURE OF LIQUID METALLIC-FILMS (REPRINTED FROM J SURFACE SCI, VOL 159, PG 69-82, 1985)

被引:0
|
作者
DERJAGUIN, BV
ROLDUGHIN, VI
机构
[1] Institute of Physical Chemistry, the Academy of Sciences, the USSR, Moscow, 117915
关键词
D O I
10.1016/0079-6816(92)90049-N
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We have found the electron density of states in a thin liquid metallic film for an arbitrary form of the boundary conditions for the wavefunctions of the electrons on the film surface. Assuming a Fermi distribution of the electron energies, we have calculated the thermodynamic characteristics of the film and determined the electronic component of the disjoining pressure. It has been shown that the ambient medium and the state of the surface determine the value and the sip of the electronic component of the disjoining pressure. We have determined the conditions for which a stable state of liquid metallic films is ensured.
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页码:218 / 231
页数:14
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