ENHANCED STEREOSELECTIVITY IN AQUEOUS INTRAMOLECULAR HETERO-DIELS-ALDER CYCLOADDITION OF CHIRAL ACYLNITROSO COMPOUNDS

被引：31
|
作者：
NARUSE, M [1 ]
AOYAGI, S [1 ]
KIBAYASHI, C [1 ]
机构：
[1] TOKYO COLL PHARM,HACHIOJI,TOKYO 19203,JAPAN
来源：
TETRAHEDRON LETTERS | 1994年 / 35卷 / 04期
关键词：
D O I：
10.1016/S0040-4039(00)75847-3
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
In an aqueous medium, intramolecular hetero Diels-Alder cycloadditions of the chiral acylnitroso compounds, generated from the chiral hydroxamic acids by in situ periodate oxidation, shows a pronounced enhancement of the trans selectivity compared with the results obtained by employing nonaqueous conditions.
引用
收藏
页码：595 / 598
页数：4
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