SYNTHETIC METHODS AND REACTIONS .157. REDUCTIVE ALKYLATION AND REDUCTION OF TERTIARY, SECONDARY, AND BENZYLIC ALCOHOLS WITH TRIMETHYLBORON, TRIETHYLBORON, AND TRIISOPROPYLBORON TRIFLUOROMETHANESULFONIC (TRIFLIC) ACID

被引:7
|
作者
OLAH, GA [1 ]
WU, AH [1 ]
FAROOQ, O [1 ]
机构
[1] UNIV SO CALIF,DEPT CHEM,LOS ANGELES,CA 90089
来源
JOURNAL OF ORGANIC CHEMISTRY | 1991年 / 56卷 / 08期
关键词
D O I
10.1021/jo00008a035
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Tertiary, secondary, and benzylic alcohols were reductively alkylated and reduced with trimethyl-, triethyl-, and triisopropylboron/trifluoromethanesulfonic (triflic) acid. A postulated mechanism for the reactions is discussed.
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页码:2759 / 2761
页数:3
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