STRUCTURAL EFFECTS ON THE THERMOCHEMICAL PROPERTIES OF CARBONYL-COMPOUNDS .2. ENTHALPIES OF COMBUSTION, VAPOR-PRESSURES AND ENTHALPIES OF SUBLIMATION, AND STANDARD ENTHALPIES OF FORMATION IN THE GASEOUS-PHASE, OF 1-ADAMANTYL METHYL KETONE AND OF 1,1'-DIADAMANTYL KETONE

The energies of combustion of 1-adamantyl methyl ketone, and 1,1'-diadamantyl ketone have been determined using a static bomb calorimeter. The vapour pressures have been measured over a temperature range of about 17K by the Knudsen-effusion technique. From the experimental results the following quantities for the two compounds, at T = 298.15K, have been derived:. © 1992 Academic Press Limited All rights reserved.