In view of the greater accuracy of the omega HEM correlation and the resulting conservative PR valve sizing (relative to the traditional PR valve sizing methods), the omega HEM-based flow calculations are recommended for all situations where flashing or two-phase flow occurs within the PR valve. However, as with any correlation, the accuracy of the omega HEM correlation results drops as the system to which it is applied diverges from the data used to develop it. Analysis of 15 different systems representative of actual refinery streams indicate that for fluids with a wide boiling range and for very non-ideal systems such as those containing hydrogen, the HEM correlation underpredicts the mass flux significantly (i.e. overpredicts the PR valve size). Since the large deviations are on the conservative side, the procedure will result in excessively large PR valves that may cause problems because of chattering of the PR valves, but would not present potential for vessel failure. The majority of the deviations are a result of the fact that the simplifying assumptions built into the correlation for single component do not truly characterize the actual flashing behaviour of many multicomponent fluids. The alternative approach presented, in which the correlation parameter omega is based on the actual flashing behaviour, eliminates nearly all the deviations and significantly improves the results of the correlation regardless of the system analysed. For trouble systems (those containing more than 0.1 wt% hydrogen and for some multicomponent fluids with a nominal boiling range greater than 80-degeres-C (150-degrees-F), the alternative approach should be used to define the correlation parameter omega. Use of this alternative approach is valid for any system (and will improve the accuracy of the correlation) but does require an additional flash calculation. However, for other systems the original formulation of omega is adequate and can be used.