MG-PROMOTED REDUCTIVE CROSS-COUPLING OF CARBONYL-COMPOUNDS WITH TRIMETHYLSILYL CHLORIDE

被引：11
|
作者：
ISHINO, Y [1 ]
MAEKAWA, H [1 ]
TAKEUCHI, H [1 ]
SUKATA, K [1 ]
NISHIGUCHI, I [1 ]
机构：
[1] ORIENT CHEM IND LTD, NEYAGAWA, OSAKA 572, JAPAN
来源：
CHEMISTRY LETTERS | 1995年 / 09期
关键词：
D O I：
10.1246/cl.1995.829
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Mg-promoted cross-coupling of aromatic carbonyl compounds with trimethylsilyl chloride (TMSCl) in DMF at room temperature brought about reductive carbon-silicon bond formation to give the corresponding alpha-trimethylsilylalkyl trimethylsilyl ethers selectively in good yields. The reaction may be initiated through electron transfer from Mg metal to the carbonyl compounds.
引用
收藏
页码：829 / 830
页数：2
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