STRUCTURE-REACTIVITY ASPECTS OF NITROALKYL ACETATE HYDROLYSIS

被引：2
|
作者：
GALLIS, DE
ACKEN, BJ
WARSHAW, JA
RICHARDSON, AL
CRIST, DR
CICHRA, DA
机构：
[1] GEORGETOWN UNIV,DEPT CHEM,WASHINGTON,DC 20057
[2] USN,CTR SURFACE WARFARE,DIV ENERGET MAT,SILVER SPRING,MD 20903
来源：
JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 20期
关键词：
D O I：
10.1021/jo00307a024
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
In the first systematic study of hydrolysis of nitroalkyl esters, it was found that hydrolysis of seven dinitro-and trinitroalkyl acetates follow first-order kinetics in the presence of either strong acid (HC104) or acetate (A-) buffers. The observed rate constant is given by. © 1990, American Chemical Society. All rights reserved.
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收藏
页码：5510 / 5515
页数：6
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