SILAFUNCTIONAL COMPOUNDS IN ORGANIC-SYNTHESIS .36. A NOVEL DEOXYGENATION FROM ALPHA,BETA-EPOXY SILANES TO VINYLSILANES BY THE COPPER-CATALYZED GRIGNARD REACTIONS - A DRAMATIC EFFECT BY ALKOXY GROUPS ON SILICON

被引：16

作者：

TAMAO, K ^{[1
]}

NAKAJO, E ^{[1
]}

ITO, Y ^{[1
]}

机构：

[1] KYOTO UNIV,FAC ENGN,DEPT SYNTHET CHEM,KYOTO 606,JAPAN

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1988年 / 53卷 / 02期

关键词：

D O I：

10.1021/jo00237a034

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

引用

页码：414 / 417

页数：4

共 7 条

[1] SILAFUNCTIONAL COMPOUNDS IN ORGANIC-SYNTHESIS .35. SILAFUNCTIONAL ALPHA,BETA-EPOXY SILANES - TRANSFORMATION INTO ERYTHRO AND THREO 1,2-DIOL SKELETONS AND ITS APPLICATION TO THE SYNTHESIS OF (+/-)-EXO-BREVICOMIN
TAMAO, K
NAKAJO, E
ITO, Y
JOURNAL OF ORGANIC CHEMISTRY, 1987, 52 (19): : 4412 - 4414
[2] ALPHA,BETA-EPOXY SULFOXIDES AS USEFUL INTERMEDIATES IN ORGANIC-SYNTHESIS .6. A NOVEL SYNTHESIS OF EPOXIDES AND ALLYLIC ALCOHOLS FROM CARBONYL-COMPOUNDS THROUGH ALPHA,BETA-EPOXY SULFOXIDES
SATOH, T
KANEKO, Y
YAMAKAWA, K
TETRAHEDRON LETTERS, 1986, 27 (21) : 2379 - 2382
[3] SILAFUNCTIONAL COMPOUNDS IN ORGANIC-SYNTHESIS .24. ASYMMETRIC-SYNTHESIS VIA CHIRAL SILICON REAGENTS - CHIRAL ALPHA-HYDROXYALKYL ANION EQUIVALENTS FROM VINYLSILANES CONTAINING OPTICALLY-ACTIVE AMINO OR ALKOXY GROUPS ON SILICON
TAMAO, K
KANATANI, R
KUMADA, M
TETRAHEDRON LETTERS, 1984, 25 (18) : 1913 - 1916
[4] ALPHA-BETA-EPOXY SULFOXIDES AS USEFUL INTERMEDIATES IN ORGANIC-SYNTHESIS .12. MAGNESIUM SALT-INDUCED OPENING OF ALPHA,BETA-EPOXY SULFOXIDES - A SYNTHESIS OF ALPHA-CHLORO KETONES, ALPHA-ALKOXY KETONES, AND ALPHA,BETA-UNSATURATED KETONES FROM CARBONYL-COMPOUNDS THROUGH ALPHA,BETA-EPOXY SULFOXIDES
SATOH, T
SUGIMOTO, A
YAMAKAWA, K
CHEMICAL & PHARMACEUTICAL BULLETIN, 1987, 35 (11) : 4632 - 4636
[5] ALPHA,BETA-EPOXY SULFOXIDES AS USEFUL INTERMEDIATES IN ORGANIC-SYNTHESIS .7. A NOVEL SYNTHESIS OF ALPHA,BETA-UNSATURATED GAMMA-HYDROXY CARBONYL-COMPOUNDS FROM ENONES WITH CARBON HOMOLOGATION
SATOH, T
MOTOHASHI, S
YAMAKAWA, K
TETRAHEDRON LETTERS, 1986, 27 (25) : 2889 - 2892
[6] ALPHA,BETA-EPOXY SULFOXIDES AS USEFUL INTERMEDIATES IN ORGANIC-SYNTHESIS .28. A NOVEL SYNTHESIS INCLUDING ASYMMETRIC-SYNTHESIS OF ALPHA,BETA-UNSATURATED GAMMA-HYDROXY CARBONYL-COMPOUNDS FROM ENONES WITH CARBON HOMOLOGATION
SATOH, T
MOTOHASHI, S
TOKUTAKE, N
YAMAKAWA, K
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1992, 65 (11) : 2966 - 2973
[7] ALPHA,BETA-EPOXY SULFOXIDES AS USEFUL INTERMEDIATES IN ORGANIC-SYNTHESIS .9. A NOVEL SYNTHESIS OF ALKYL VINYL KETONES AND DIVINYL KETONES FROM CARBONYL-COMPOUNDS AND 1-CHLORO-3-PHENYLTHIOPROPYL PHENYL SULFOXIDE AS A 3-CARBON HOMOLOGATING AGENT
SATOH, T
KUMAGAWA, T
SUGIMOTO, A
YAMAKAWA, K
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1987, 60 (01) : 301 - 310

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