LOWEST ENERGY TRIPLET-STATES OF GROUP VB HYDRIDES - NH3 (ND3) AND PH3

被引：11
|
作者：
BENARFA, M
TRONC, M
机构：
[1] Laboratoire de Chimie Physique1 1 Associé au CNRS URA 176., Université Pierre et Marie Curie, 75231 Paris Cedex 05
来源：
CHEMICAL PHYSICS | 1991年 / 155卷 / 01期
关键词：
D O I：
10.1016/0301-0104(91)87014-M
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Low energy electron impact and high scattering an e energy loss spectra allowed for observation of the lowest energy triplet states of NH3, ND3 and PH3. Three bending levels of the 3A2" states of NH3 have been observed at 5.36, 5.48 and 5.60 eV. In ND3 four levels have been observed beginning at 5.42 eV with a spacing of 0.093 eV. In PH3 a low intensity broad and structureless band with maximum around 6 eV is attributed to the 3A2" state.
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页码：143 / 148
页数：6
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