AN IR STUDY OF THE ZIEGLER SYSTEM CO(ACAC)3/MG(N-BUTYL)2 IN THF

被引:0
|
作者
LUHDER, K
BOHMER, WH
STOLDT, I
MADEJA, K
机构
[1] Department of Chemistry, Ernst-Moritz-Arndt University of, Greifswald
来源
关键词
D O I
10.1007/BF02070060
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Applying IR spectroscopy for studying the Ziegler system Co(acac)3/Mg (Bu)2 (Bu=n-butyl) in tetrahydrofuran, it could be shown that the following reactions take place: reduction of cobalt(III), exchange of the acetylacetonate groups and their interaction with Mg(Bu)2.
引用
收藏
页码:9 / 15
页数:7
相关论文
共 50 条
  • [1] POLYMERIZATION OF METHYLMETHACRYLATE BY ORGANOMETALLIC COMPOUNDS .7. N-BUTYL MAGNESIUM BROMIDE-DI-N-BUTYL MAGNESIUM SYSTEM IN THF + TOLUENE SOLUTION
    BATEUP, BO
    ALLEN, PEM
    EUROPEAN POLYMER JOURNAL, 1977, 13 (10) : 761 - 768
  • [2] Calorimetric study of block-copolymers of poly(n-butyl acrylate) and gradient poly(n-butyl acrylate-co-methyl methacrylate)
    Buzin, AI
    Pyda, M
    Costanzo, P
    Matyjaszewski, K
    Wunderlich, B
    POLYMER, 2002, 43 (20) : 5563 - 5569
  • [3] A Single-Crystal Model for MgCl2-Electron Donor Support Materials: [Mg3Cl5(THF)4Bu]2 (Bu = n-Butyl)
    Pirinen, Sami
    Koshevoy, Igor O.
    Denifl, Peter
    Pakkanen, Tuula T.
    ORGANOMETALLICS, 2013, 32 (15) : 4208 - 4213
  • [4] Synthesis of [2,3-H-3]-n-butyl alcohol
    Huang, DZWW
    Wang, W
    JOURNAL OF LABELLED COMPOUNDS & RADIOPHARMACEUTICALS, 1997, 39 (04): : 349 - 352
  • [5] Synthesis of [2,3-3H]-n-butyl alcohol
    China Institute of Atomic Energy, P.O.Box 275, Beijing, China
    J. LABEL. COMPD. RADIOPHARM., 4 (349-352):
  • [6] SEPARATION OF BORON ISOTOPES .3. N-BUTYL SULFIDE-BF3 SYSTEM
    PALKO, AA
    JOURNAL OF CHEMICAL PHYSICS, 1959, 30 (05): : 1187 - 1189
  • [7] REACTION-MECHANISM AND PROPERTIES OF COMPOUNDS FORMED IN SYSTEM FECL3+MG+THF+N2
    JEZOWSKA.B
    SOBOTA, P
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1972, 46 (02) : 339 - 343
  • [8] Research on the photocatalytic removal of N-butyl and isobutyl xanthates in the TiO2 suspension system
    Chen, JH
    Zhao, CH
    Gong, ZQ
    FRONTIERS ON SEPARATION SCIENCE AND TECHNOLOGY, 2004, : 1010 - 1018
  • [9] Thermolysis specifics of Tin(IV) and Tin(II) complex derivatives: Thermolysis of (Acac)2SnX2 (X = Cl, N3), (CO)5MSnCl2(thf) (M = Cr, Mo, W), (CO)5MSn(Acac)2, (CO)5MSn(SCN)2, (CH3)4N(CO)5MoSnCl3 (M = Cr, W), and (CO)2MnCpSnCl2(thf)
    Zh. B. Dobrokhotova
    P. S. Koroteev
    V. M. Novotortsev
    M. P. Egorov
    O. M. Nefedov
    Russian Journal of Inorganic Chemistry, 2007, 52 : 1109 - 1119
  • [10] Thermolysis specifics of Tin(IV) and Tin(II) complex derivatives:: Thermolysis of (Acac)2SnX2 (X = Cl, N3), (CO)5MSnCl2(thf) (M = Cr, Mo, W), (CO)5MSn(Acac)2, (CO)5MSn(SCN)2, (CH3)4N(CO)5MoSnCl3 (M = Cr, W), and (CO)2MnCpSnCl2(thf)
    Dobrokhotova, Zh. B.
    Koroteev, P. S.
    Novotortsev, V. M.
    Egorov, M. P.
    Nefedov, O. M.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2007, 52 (07) : 1109 - 1119