CHARACTERIZATION OF ETHOXYLATED FATTY ALCOHOLS USING LIQUID-CHROMATOGRAPHY WITH DENSITY AND REFRACTIVE-INDEX DETECTION .1. QUANTITATIVE-ANALYSIS OF PURE HOMOLOGOUS SERIES BY SIZE-EXCLUSION CHROMATOGRAPHY

被引:25
|
作者
TRATHNIGG, B [1 ]
THAMER, D [1 ]
YAN, X [1 ]
MAIER, B [1 ]
HOLZBAUER, HR [1 ]
MUCH, H [1 ]
机构
[1] CTR MACROMOLEC CHEM,BERLIN,GERMANY
关键词
D O I
10.1016/0021-9673(93)80292-G
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
Ethoxylated fatty alcohols can be characterized by two-dimensional chromatography with LC under critical conditions as the first and size-exclusion chromatography (SEC) as the second dimension. The dependence of response factors on the chemical composition can be compensated by two different approaches. The results obtained are in good agreement. The SEC calibrations for the individual homologous series showed considerable differences, hence for each fraction the corresponding calibration should be used.
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页码:365 / 375
页数:11
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