NUCLEAR-MAGNETIC-RESONANCE SPECTROSCOPIC STUDY ON THE GRAFTING OF ETHYLENE-OXIDE ONTO THE INTERLAYER SURFACE OF GAMMA-ZIRCONIUM PHOSPHATE

被引:3
|
作者
NAKANO, H
OHNO, T
YAMANAKA, S
机构
关键词
D O I
10.1246/cl.1994.9
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The reaction products of gamma-zirconium phosphate with ethylene oxide were analyzed by solid-state P-31 magic-angle spinning (MAS) NMR, and P-31 and C-13 solution NMR spectroscopy. Gamma-Zirconium phosphate can be formulated as Zr(PO4)(H2PO4).2H2O. Ethylene oxide molecules react with the interlayer H2PO4 groups, forming diester derivatives of ethylene and/or diethylene glycols.
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页码:9 / 12
页数:4
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