Specific Adsorption of Aspartic Acid on Iron (III) and Nickel (II) Oxides

被引：2
|
作者：
Dmitrieva, I. B. [1 ]
Chukhno, A. S. [1 ]
Rodionova, E. Y. [2 ]
Novichkov, R. V. [1 ]
机构：
[1] St Petersburg Univ, Chem Res Inst, 2,Univ Pr,Petrodvorets, St Petersburg 198904, Russia
[2] St Petersburg Acad Chem & Pharmacol, Phys & Colloid Chem Dept, St Petersburg 197376, Russia
来源：
EURASIAN CHEMICO-TECHNOLOGICAL JOURNAL | 2012年 / 14卷 / 04期
关键词：
D O I：
10.18321/ectj126
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The dependences of zeta-potential and adsorption of aspartic acid on NiO and Fe2O3 oxides were investigated as a function of aspartic acid concentration, pH and adsorption time using microelectrophoresis and potentiometric titration methods. Shifting of pH(IEP) (the isoelectric point or IEP) towards the acid zone for Fe2O3 and towards the base zone for NiO in the solutions of aspartic acid in comparison with HCl shows the presence of specific adsorption of aspartic acid anion and cation forms on the surfaces of Fe2O3 and NiO oxides, respectively. The complexation process of Fe(III) ions with aspartic acid in the bulk solution and on the oxide surface was examined by spectrophotometer. It was determined that Fe(III) ions form complexes with aspartic acid in the bulk solution.
引用
收藏
页码：299 / 304
页数：6
相关论文
共 50 条
  • [1] Specific adsorption of barbituric acid on ferric(III) and nickel(II) oxides
    Dmitrieva, IB
    Prokopovich, PP
    Tikhomolova, KP
    Starov, V
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2004, 239 (1-3) : 19 - 24
  • [2] Reactions of Nickel(II), Nickel(II,III), and Iron(III) oxides in liquid ammonia
    Holt, RB
    Watt, GW
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1943, 65 : 988 - 989
  • [3] Dissolution Kinetics of Nickel(II) and Nickel(III) Oxides in Acid Media
    N. M. Pichugina
    A. M. Kutepov
    I. G. Gorichev
    A. D. Izotov
    B. E. Zaitsev
    Theoretical Foundations of Chemical Engineering, 2002, 36 : 485 - 494
  • [4] Dissolution kinetics of nickel(II) and nickel(III) oxides in acid media
    Pichugina, NM
    Kutepov, AM
    Gorichev, IG
    Izotov, AD
    Zaitsev, BE
    THEORETICAL FOUNDATIONS OF CHEMICAL ENGINEERING, 2002, 36 (05) : 485 - 494
  • [5] SURFACE-PROPERTIES OF BINARY HYDROXIDES AND OXIDES OF NICKEL(II)-IRON(III) WITH RESPECT TO PYRIDINE ADSORPTION
    VERESHCHAGINA, LA
    EGOROVA, SA
    TUGUSHEV, RE
    BAKHOVSKAYA, SM
    BOLOTINA, NE
    COLLOID JOURNAL OF THE USSR, 1986, 48 (01): : 109 - 112
  • [6] SORPTIVE LEACHING OF A MIXTURE OF ZINC, IRON(III), COBALT(II, III), AND NICKEL(II) OXIDES
    NIKOLAEVA, RB
    PASHKOV, GL
    SAIKOVA, SV
    JOURNAL OF APPLIED CHEMISTRY OF THE USSR, 1992, 65 (12): : 2226 - 2229
  • [7] Investigation of the mechanism and kinetics of dissolution of nickel(II) and nickel(III) oxides in sulfuric acid
    Yu. S. Ageeva
    I. G. Gorichev
    A. D. Izotov
    N. M. Pichugina
    Theoretical Foundations of Chemical Engineering, 2006, 40 : 147 - 154
  • [8] Investigation of the mechanism and kinetics of dissolution of nickel(II) and nickel(III) oxides in sulfuric acid
    Ageeva, YS
    Gorichev, IG
    Izotov, AD
    Pichugina, NM
    THEORETICAL FOUNDATIONS OF CHEMICAL ENGINEERING, 2006, 40 (02) : 147 - 154
  • [9] Iron isotope fractionation during adsorption of Fe(II) on Fe(III) oxides
    Teutsch, N
    von Gunten, U
    Hofstetter, TB
    Halliday, AN
    GEOCHIMICA ET COSMOCHIMICA ACTA, 2004, 68 (11) : A361 - A361
  • [10] Adsorption and Oxidation of As(III) on Iron (Hydro)Oxides
    Zhao, Zhixi
    Guan, Ming
    Zeng, Han
    Chen, Ping
    WATER ENVIRONMENT RESEARCH, 2018, 90 (06) : 483 - 489
12345