Olive fruits were sampled at various stages during their progress through the ''California Black Ripe'' process. Analysis of cell,walls prepared from these fruits indicated that processing was accompanied by general solubilization of polysaccharides and that pectins and a noncellulosic glucan component were most clearly affected. Soluble polysaccharides accumulated in processing liquids. Analysis of these and of polysaccharides extracted fr om cell walls suggests that the polymer most extensively solubilized and eluted during processing is a relatively unbranched pectin.