CAROTANOIDS AND AN ACORANOID FROM ROSA-RUGOSA LEAVES

被引：23
|
作者：
HASHIDOKO, Y
TAHARA, S
MIZUTANI, J
机构：
[1] Department of Agricultural Chemistry, Faculty of Agriculture, Hokkaido University, Kita-ku, Sapporo
来源：
PHYTOCHEMISTRY | 1991年 / 30卷 / 11期
关键词：
ROSA-RUGOSA; ROSACEAE; LEAVES; SESQUITERPENES; CAROTANOID; DAUCANOID; ACORANOID;
D O I：
10.1016/0031-9422(91)80099-M
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
In the investigation of minor sesquiterpenoids in Rosa rugosa leaves, 11 novel sesquiterpenes, eight carotane aldehydes, two carotane acids and an acoranoid, were isolated and their structures elucidated by means of chemical and spectroscopic methods. The present study showed that R. rugosa is a major source of C-14-oxygenated carotanoids. Factors associated with stereoselective oxygen-introduction in epoxidation and/or peroxidation of the carotane skeleton is also discussed.
引用
收藏
页码：3729 / 3739
页数：11
相关论文
共 50 条
  • [1] SESQUITERPENOIDS FROM ROSA-RUGOSA LEAVES
    HASHIDOKO, Y
    TAHARA, S
    MIZUTANI, J
    PHYTOCHEMISTRY, 1993, 32 (02) : 387 - 390
  • [2] ISOLATION OF 4 NOVEL CAROTANOIDS AS POSSIBLE METABOLITES OF RUGOSIC ACID-A IN ROSA-RUGOSA LEAVES
    HASHIDOKO, Y
    TAHARA, S
    MIZUTANI, J
    AGRICULTURAL AND BIOLOGICAL CHEMISTRY, 1991, 55 (04): : 1049 - 1053
  • [3] NOVEL BISABOLANOIDS IN ROSA-RUGOSA LEAVES
    HASHIDOKO, Y
    TAHARA, S
    MIZUTANI, J
    ZEITSCHRIFT FUR NATURFORSCHUNG C-A JOURNAL OF BIOSCIENCES, 1991, 46 (5-6): : 349 - 356
  • [4] HIGHLY OXYGENATED BISABOLANOIDS IN ROSA-RUGOSA LEAVES
    HASHIDOKO, Y
    TAHARA, S
    IWAYA, N
    MIZUTANI, J
    ZEITSCHRIFT FUR NATURFORSCHUNG C-A JOURNAL OF BIOSCIENCES, 1991, 46 (5-6): : 357 - 363
  • [5] CHANGES IN CAROTANE SESQUITERPENOIDS IN ROSA-RUGOSA LEAVES
    HASHIDOKO, Y
    IWAYA, N
    TAHARA, S
    MIZUTANI, J
    NIPPON NOGEIKAGAKU KAISHI-JOURNAL OF THE JAPAN SOCIETY FOR BIOSCIENCE BIOTECHNOLOGY AND AGROCHEMISTRY, 1991, 65 (10): : 1483 - 1488
  • [6] SESQUITERPENE HYDROCARBONS IN GLANDULAR TRICHOME EXUDATE OF ROSA-RUGOSA LEAVES
    HASHIDOKO, Y
    TAHARA, S
    MIZUTANI, J
    ZEITSCHRIFT FUR NATURFORSCHUNG C-A JOURNAL OF BIOSCIENCES, 1992, 47 (5-6): : 353 - 359
  • [7] 2-PHENOXYCHROMONES AND A STRUCTURALLY RELATED FLAVONE FROM LEAVES OF ROSA-RUGOSA
    HASHIDOKO, Y
    TAHARA, S
    MIZUTANI, J
    PHYTOCHEMISTRY, 1991, 30 (11) : 3837 - 3838
  • [8] ECOFORMS OF ROSA-RUGOSA THUNB
    APALIA, DK
    SOVIET JOURNAL OF ECOLOGY, 1979, 10 (06) : 571 - 572
  • [9] ROSA-RUGOSA - VERRIER,S
    LACY, A
    NEW YORK TIMES BOOK REVIEW, 1991, : 43 - 43
  • [10] LONG-CHAIN ALKYL ESTERS OF 4'-HYDROXYCINNAMIC ACIDS FROM LEAVES OF ROSA-RUGOSA
    HASHIDOKO, Y
    TAHARA, S
    MIZUTANI, J
    PHYTOCHEMISTRY, 1992, 31 (09) : 3282 - 3283
12345