CHARGE-TRANSFER SPECTRA OF ORGANOMETALLIC COMPLEXES .8. ENERGY CONTRIBUTIONS TO THE FORMATION OF A DONOR-ACCEPTOR COMPLEX AND TO THE ELECTRON-TRANSFER IN THE INTERACTION BETWEEN TRIALKYLTIN DONORS R3SNX (X = NCS, BR) AND THE ACCEPTORS I-2 AND TCNE

被引：0

作者：

VERBIEST, P ^{[1
]}

VERDONCK, L ^{[1
]}

VANDERKELEN, GP ^{[1
]}

机构：

[1] STATE UNIV GHENT,ALGEMENE ANORGAN CHEM LAB,KRIJGSLAAN 281,B-9000 GHENT,BELGIUM

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 1992年 / 48卷 / 05期

关键词：

D O I：

10.1016/0584-8539(92)80206-C

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The enthalpies of formation for charge transfer complexes of the type [R3SnNCS-I2] (R = Et, iPr), [Et3SnNCS-TCNE] and [R3SnBr-I2] (R = Me, Et) have been determined by calorimetric measurements. The data are analyzed using Mulliken's resonance structure theory, to produce the different energy contributions to the charge transfer interaction in these complexes.

引用

页码：625 / 629

页数：5

共 2 条

[1] CHARGE-TRANSFER SPECTRA OF ORGANOMETALLIC COMPLEXES .3. ENERGY CONTRIBUTIONS TO THE FORMATION OF A DONOR-ACCEPTOR COMPLEX AND TO THE ELECTRON-TRANSFER IN THE INTERACTION BETWEEN TRIALKYLTIN IODIDES AND IODINE IN CARBON-TETRACHLORIDE SOLUTIONS
HOSTE, S
HERMAN, GG
LIPPENS, W
VERDONCK, L
VANDERKELEN, GP
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1985, 41 (07): : 925 - 932
[2] Exclusive formation of 1:1 and 2:2 complexes between cucurbit[8]uril and electron donor-acceptor molecules induced by host-stabilized charge-transfer interactions
Ko, Young Ho
Kim, Kyungpil
Kim, Eunju
Kim, Kimoon
SUPRAMOLECULAR CHEMISTRY, 2007, 19 (4-5) : 287 - 293

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