MULTIDENTATE PHENYL-BONDED PHASES IN HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY

被引:16
|
作者
JINNO, K [1 ]
YAMAMOTO, K [1 ]
KUWAMOTO, T [1 ]
NAGASHIMA, H [1 ]
UEDA, T [1 ]
TAJIMA, S [1 ]
KIMURA, E [1 ]
ITOH, K [1 ]
FETZER, JC [1 ]
BIGGS, WR [1 ]
机构
[1] CHEVRON RES & TECHNOL CO,RICHMOND,CA 94802
关键词
COLUMN LIQUID CHROMATOGRAPHY; MOLECULAR RECOGNITION; MULTIDENTATE PHENYL-BONDED PHASES; PAHS;
D O I
10.1007/BF02268372
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
New multidentate phenyl-bonded phases (MPBPs) were synthesized and evaluated the chromatographic retention behaviour with polycyclic aromatic hydrocarbons as sample probes in high-performance liquid chromatography. The new MPBPs show different retention characteristics from the previously synthesized MPBP, designated TP. Nevertheless, the results indicate that the retention mechanism is still the same as the TP phase: the size and shape of the solute molecule can be recognized by a cavity-like space formed by the methyl groups and phenyl rings of MPBPs.
引用
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页码:381 / 385
页数:5
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