TETRATHIORHENATE(VI), RES4(2-) - SPECTROELECTROCHEMICAL CHARACTERIZATION (UV VIS IR) OF A SMALL NEW D(1) SYSTEM AND OF ITS TETRAKIS(2,2'-BIPYRIDINE)DIRUTHENIUM(II) COMPLEX (EPR)

被引：24

作者：

SCHAFER, R

KAIM, W

MOSCHEROSCH, M

KREJCIK, M

机构：

[1] UNIV STUTTGART, INST ANORGAN CHEM, PFAFFENWALDRING 55, W-7000 STUTTGART 80, GERMANY

[2] CZECHOSLOVAK ACAD SCI, J HEYROVSKY INST PHYS CHEM & ELECTROCHEM, CS-18223 PRAGUE, CZECHOSLOVAKIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 11期

关键词：

D O I：

10.1039/c39920000834

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

ReS42- is the first d1 tetrathiometallate persistent enough to be studied with respect to change transfer, ligand field and IR vibrational spectra via spectroelectrochemistry; an EPR spectrum could only be detected of its trinuclear derivative [(bpy)2Ru(mu-ReS4)Ru(bpy)2]2+ (bpy = 2,2'-bipyridine) at 4 K.

引用

页码：834 / 835

页数：2

共 38 条

[1] ELECTROCHEMISTRY AND SPECTROELECTROCHEMISTRY (EPR, UV-VIS-NEAR-IR) OF PLATINUM(II) 2,2'-BIPYRIDINE AND RING-METALATED BIPYRIDINE COMPLEXES - PTII(L-) AND PTI(L-) BUT NOT PTI(L)
BRATERMAN, PS
SONG, JI
WIMMER, FM
WIMMER, S
KAIM, W
KLEIN, A
PEACOCK, RD
INORGANIC CHEMISTRY, 1992, 31 (24) : 5084 - 5088
[2] Unusual electrochemical and spectroscopic behavior in a ligand-bridged binuclear complex of ruthenium(II): Tetrakis(2,2'-bipyridine)-(mu-2,4,6-tris(2-pyridyl)triazine) diruthenium(II)
Berger, RM
Ellis, DD
INORGANICA CHIMICA ACTA, 1996, 241 (02) : 1 - 4
[3] Syntheses, characterization and DNA binding of mono- and diruthenium(II) complexes containing 2,2′-bis(1,2,4-triazino[5,6-f]phenanthren-3-yl)-4,4′-bipyridine and 2,2′-bipyridine ligands
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INORGANICA CHIMICA ACTA, 2005, 358 (04) : 1231 - 1236
[4] Synthesis, UV/vis, FT-IR and Mossbauer spectroscopic characterization and molecular structure of the Bis[4-(2-aminoethyl) morpholine](tetrakis(4-metoxyphenyl)porphyrinato) iron(II) complex
Hassen, Leila Ben Haj
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[5] Antibacterial Activities and Nuclease Properties of Two New Ternary Copper(II) Complexes with 2-(4′-Thiazolyl)-benzimidazole and 2,2′-Bipyridine/1,10-phenanthroline
Ren Xiangxiang
Chen Jiayang
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CHINESE JOURNAL OF CHEMISTRY, 2011, 29 (07) : 1380 - 1388
[6] Acetato and formato copper(II) complexes with 4,4′-dimethyl-2,2′-bipyridine and 5,5′-dimethyl-2,2′-bipyridine: Synthesis, crystal structure, magnetic properties and EPR results. A new 1D polymeric water chain
Barquin, Montserrat
Cocera, Nerea
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Pinilla, Elena
Seco, Jose M.
Torres, Maria R.
INORGANICA CHIMICA ACTA, 2010, 363 (01) : 127 - 133
[7] A NEW TETRATUNGSTATE, [W4O4CL10 (NBU(T)4]2-, AND ITS DEGRADATION TO THE MONONUCLEAR COMPLEX [WOCL2(NBU(T) (BIPY)] OR [WCL2(NBU(T)2(BIPY)] (BIPY = 2,2'-BIPYRIDINE)
CLEGG, W
ERRINGTON, J
HOCKLESS, DCR
REDSHAW, C
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (13): : 1965 - 1971
[8] A dinuclear bis(bipyridine)ruthenium(II) complex, [(bpy)2RuII{L2-}RuII(bpy)2]2+, incorporating an unusual non-innocent bridging ligand containing a p-benzoquinonediimine fragment:: synthesis, structure, redox, and UV/VIS/NIR and EPR spectroelectrochemical properties
Chakraborty, S
Laye, RH
Paul, RL
Gonnade, RG
Puranik, VG
Ward, MD
Lahiri, GK
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (06): : 1172 - 1179
[9] Synthesis, structure and DNA-binding studies on the 2-(3-chlorophenyl)imidazo[4,5-f]1,10-phenanthroline-bis(2,2′-bipyridine)-ruthenium(II) complex
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Wu, JZ
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TRANSITION METAL CHEMISTRY, 1999, 24 (03) : 263 - 267
[10] Synthesis and Characterization of a New Ligand 2-(4,5-Dihydro-2-thiazolyl)-6-methoxylbenzothiazole and Its Dinuclear Co(II) Complex
Xiao Da-Wei
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Li Jian-Li
Shi Zhen
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2010, 29 (11) : 1712 - 1716

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