PHOTOLYSIS OF ETHYL CHLORIDE AT 121.6-NM

被引：0
|
作者：
CHOI, SS
OH, DG
KIM, SK
JUNG, KH
机构：
[1] KOREA INST SCI & TECHNOL, CTR MOLEC SCI, POB 150 CHONGYANG, SEOUL 130650, SOUTH KOREA
[2] KOREA INST SCI & TECHNOL, DEPT CHEM, SEOUL 130650, SOUTH KOREA
[3] SEOUL NATL UNIV, DEPT CHEM, SEOUL 151742, SOUTH KOREA
来源：
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 1992年 / 64卷 / 02期
关键词：
D O I：
10.1016/1010-6030(92)85101-Y
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The photolysis of ethyl chloride at 121.6 nm was studied over the pressure range 60-4000 Pa at room temperature using a hydrogen atom resonance lamp. The pressure effect was investigated with CO2 and SF6. The scavenger effect of the reaction was also observed by adding NO gas. The major products of the reaction were CH4, C2H2, C2H4 and C2H6. The branching ratios between the elimination and the radical processes were found to be 0.68-0.32. The fraction of hot ethylene (above the critical energy) was found to be about 30%.
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页码：135 / 143
页数：9
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