EXPERIMENTAL-EVIDENCE FOR AN ISOMERIC TRANSITION OF SIZE-SELECTED METHANOL HEXAMERS

被引：40

作者：

BUCK, U

ETTISCHER, I

机构：

[1] Max-Planck-Institut für Strömungsforschung

来源：

JOURNAL OF CHEMICAL PHYSICS | 1994年 / 100卷 / 09期

关键词：

D O I：

10.1063/1.467014

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We have measured the predicted isomeric transition between the two energetically lowest lying isomers of S-6 and C-2 symmetry of (CH3OH)(6). The clusters are size selected by momentum transfer in collisions with He, and identified by their infrared spectra. The transition occurs at a nozzle temperature of 368 K corresponding to a cluster temperature of 23 K.

引用

页码：6974 / 6976

页数：3

共 27 条

[1]

[Anonymous], 1979, ADV CHEM PHYS, DOI DOI 10.1002/9780470142592.CH2

[2]

BERRY RS, 1990, P INT SCH PHYS, V107, P23

[3]

BERRY RS, 1988, ADV CHEM PHYS, V70, P74

[4]

BILLING GD, 1986, CHEM PHYS, V104, P19, DOI 10.1016/0301-0104(86)80149-5