X-RAY-DIFFRACTION STUDY OF LIQUID TERTIARY BUTYL ALCOHOL AT 26-DEGREES-C

被引：83

作者：

NARTEN, AH ^{[1
]}

SANDLER, SI ^{[1
]}

机构：

[1] UNIV DELAWARE,DEPT CHEM ENGN,NEWARK,DE 19711

来源：

JOURNAL OF CHEMICAL PHYSICS | 1979年 / 71卷 / 05期

关键词：

D O I：

10.1063/1.438576

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The x-ray diffraction pattern of liquid tertiary butyl alcohol (CMe 3OH) near the melting point has been measured. The data are analyzed to yield the molecular structure. The distinct structure function H d(k) derived from the data is compared with that obtained previously for liquid neopentane (CMe4). The replacement of one methyl group in CMe4 by a hydroxyl group to produce CMe3OH results in significant changes in Hd(k). The data show clearly that hydrogen-bonded hydroxyl groups occur in liquid CMe3OH with an O⋯O distance of 2.74 Å, and that each hydroxyl group has two nearest neighbors at this distance. © 1979 American Institute of Physics.

引用

页码：2069 / 2073

页数：5

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