MONOCHROMATIC 2-BEAM MULTIPHOTON DISSOCIATION OF CF2HCL

被引：2

作者：

SIGUENZA, CL ^{[1
]}

GONZALEZDIAZ, PF ^{[1
]}

机构：

[1] CSIC,INST MATEMAT & FIS FUNDAMENTAL,E-28006 MADRID,SPAIN

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 1994年 / 50卷 / 04期

关键词：

D O I：

10.1016/0584-8539(94)80017-0

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

Infrared multiphoton dissociation induced by monochromatic two-beam excitation has been carried out by controlling the time delay between the two laser beams. The maximum dissociation yield is found to occur at time delays around 5 mus, when the absorbed energy becomes largely stochastized and an equilibrium among the distinct processes of energy relaxation is manifested. It is shown that this behaviour essentially differs from that which occurs in dichromatic multiphoton dissociation.

引用

页码：813 / 817

页数：5

共 50 条

[1] ACTIVATION OF THE INFRARED MULTIPHOTON DISSOCIATION OF CF2HCL
SIGUENZA, CL
CHEMICAL PHYSICS LETTERS, 1991, 181 (04) : 351 - 354
[2] Efficient multiphoton dissociation of CF2HCl in waveguide reactors with high selectivity
Parthasarathy, V
Sethi, S
Gantayet, LM
Nilaya, P
Biswas, DJ
Iyer, NV
Rao, KA
Sarkar, SK
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1997, 110 (01) : 11 - 15
[3] LASER INTENSITY EFFECTS IN THE IR MULTIPHOTON DISSOCIATION OF CF2HCL AND CF2CFCL
STEPHENSON, JC
KING, DS
JOURNAL OF CHEMICAL PHYSICS, 1983, 78 (04): : 1867 - 1875
[4] ISOTOPICALLY SELECTIVE MULTIPHOTON DISSOCIATION OF CF2HCL IN COLLISION CONDITIONS OF EXCITATION
AVATKOV, ON
VETSKO, VM
DZNELADZE, DI
ESADZE, GG
KAMINSKII, AV
KUDZIEV, AG
KUDZIEV, TA
HIGH ENERGY CHEMISTRY, 1988, 22 (02) : 144 - 148
[5] MULTIPHOTON DISSOCIATION OF C3F6 AND CF2HCL
SANTOS, M
SIGUENZA, C
TORRESANO, JA
GONZALEZDIAZ, PF
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1990, 46 (04) : 455 - 458
[6] CATALYTIC DISSOCIATION OF CF2HCL ON PLATINUM BLACK
MU, GR
REN, LW
LI, CL
ACTA CHIMICA SINICA, 1985, 43 (11) : 1015 - 1019
[7] REMARKS ON INFRARED MULTIPHOTON DISSOCIATION OF C3F6 AND CF2HCL WITH 2 WAVELENGTHS
SIGUENZA, C
SANTOS, M
TORRESANO, JA
PINO, A
GONZALEZDIAZ, PF
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1990, 46 (10): : 1499 - 1503
[8] Multiphoton fragmentation and ionization of CF2HCl molecules and clusters by UV radiation
V. N. Lokhman
D. D. Ogurok
E. A. Ryabov
Journal of Experimental and Theoretical Physics, 2006, 103 : 1 - 14
[9] Multiphoton fragmentation and ionization of CF2HCl molecules and clusters by UV radiation
Lokhman, V. N.
Ogurok, D. D.
Ryabov, E. A.
JOURNAL OF EXPERIMENTAL AND THEORETICAL PHYSICS, 2006, 103 (01) : 1 - 14
[10] Thermal decomposition of CF2HCl
Su, MC
Kumaran, SS
Lim, KP
Michael, JV
Wagner, AF
Dixon, DA
Kiefer, JH
DiFelice, J
JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (39): : 15827 - 15833

← 1 2 3 4 5 →