THE UTILITY OF (C5ME5)2SM IN ISOLATING CRYSTALLOGRAPHICALLY CHARACTERIZABLE ZINTL IONS - X-RAY CRYSTAL-STRUCTURE OF A COMPLEX OF (SB3)3-

被引：43

作者：

EVANS, WJ

GONZALES, SL

ZILLER, JW

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 16期

关键词：

D O I：

10.1039/c39920001138

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(C5Me5)2Sm reacts with Sb(Bu(n))3 in toluene to form [(C5Me5)2SM]3(mu-eta-2:eta-2:eta-1-Sb3)(thf) (thf = tetrahydrofuran), which contains a bent (Sb3)3- ion [114.5(1)-degrees] with an average Sb-Sb distance of 2.688(1) angstrom.

引用

页码：1138 / 1138

页数：1

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