THE STRUCTURE OF NA5TI(PO4)3

被引：41
|
作者：
KRIMI, S
MANSOURI, I
ELJAZOULI, A
CHAMINADE, JP
GRAVEREAU, P
LEFLEM, G
机构：
[1] FAC SCI BEN MSIK,DEPT CHIM,CASABLANCA,MOROCCO
[2] UNIV BORDEAUX 1,CNRS,CHIM SOLIDE LAB,F-33405 TALENCE,FRANCE
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 1993年 / 105卷 / 02期
关键词：
D O I：
10.1006/jssc.1993.1248
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The sodium titanium phosphate Na5Ti(PO4)3 crystallizes in the trigonal space group R32 (a = 9.0607(2) Å, c = 21.734(1) Å, V = 1545.3 Å3, dm = 2.84(2), dc = 2.89 Mg · m-3, Z = 6). R = 0.022 and Rw = 0.023 for 831 reflections. The structure belongs to the Nasicon-type family and is characterized by a 2-2 titanium-sodium ordering along the c axis. The four crystallographically independent sodium atoms show coordination numbers 6 and 8. The cell parameters and the cationic distribution are consistent with the rules governing the structural evolution of such types of material. © 1993 Academic Press, Inc.
引用
收藏
页码：561 / 566
页数：6
相关论文
共 50 条
  • [1] SYNTHESIS OF NA5TI(PO4)3 DIPHOSPHATE
    SLOBODYANIK, NS
    NAGORNYI, PG
    BYALKOVSKII, GD
    UKRAINSKII KHIMICHESKII ZHURNAL, 1985, 51 (07): : 770 - 771
  • [2] INVESTIGATION OF THE GLASS CRYSTAL TRANSITION OF NA5TI(PO4)3
    KRIMI, S
    MANSOURI, I
    ELJAZOULI, A
    CHAMINADE, JP
    GRAVEREAU, P
    LEFLEM, G
    JOURNAL OF ALLOYS AND COMPOUNDS, 1992, 188 (1-2) : 120 - 122
  • [3] STRUCTURE AND ION CONDUCTIVITY IN SOLIDS .5. STRUCTURE AND PROPERTIES OF THE COMPOUNDS NA3MNZR(PO4)3 AND NA3MGZR(PO4)3
    FELTZ, A
    BARTH, S
    ANDRATSCHKE, M
    JAGER, C
    JOURNAL OF THE LESS-COMMON METALS, 1988, 137 (1-2): : 43 - 54
  • [4] The crystal structure of eulytite Na3Bi5(PO4)6
    Arbib, E
    Chaminade, JP
    Darriet, J
    Elouadi, B
    SOLID STATE SCIENCES, 2000, 2 (02) : 243 - 247
  • [5] On the structure of Li3Ti2(PO4)3
    Aatiq, A
    Ménétrier, M
    Croguennec, L
    Suard, E
    Delmas, C
    JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (10) : 2971 - 2978
  • [6] CRYSTAL-STRUCTURE OF NA,TI-ORTHOPHOSPHATE, NATI2[PO4]3
    IVANOV, IA
    EGOROVTISMENKO, IK
    SIMONOV, MA
    BELOV, NV
    BELOKONEVA, EL
    DOKLADY AKADEMII NAUK SSSR, 1980, 252 (05): : 1122 - 1125
  • [7] TERNARY PHOSPHATES IN THE SYSTEMS CA3(PO4)2-NA3ND(PO4)2, CA3(PO4)2-NA3U(PO4)2, CA3(PO4)2-NA3ER(PO4)2
    LAZORYAK, BI
    IVANOV, LN
    STRUNENKOVA, TV
    GOLUBEV, VN
    VITING, BN
    INORGANIC MATERIALS, 1990, 26 (02) : 283 - 286
  • [8] Crystal Structure of Na2V2(PO4)3, an Intriguing Phase Spotted in the Na3V2(PO4)3-Na1V2(PO4)3 System
    Park, Sunkyu
    Wang, Ziliang
    Deng, Zeyu
    Moog, Iona
    Canepa, Pieremanuele
    Fauth, Francois
    Carlier, Dany
    Croguennec, Laurence
    Masquelier, Christian
    Chotard, Jean-Noel
    CHEMISTRY OF MATERIALS, 2022, 34 (01) : 451 - 462
  • [9] SYNTHESIS AND CRYSTAL-STRUCTURE OF NA5CU3(PO4)2(PO4HOP4)
    EFFENBERGER, H
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1985, 172 (1-2): : 97 - 104
  • [10] Crystal Structure of Na3MgTi(PO4)3.
    Krimi, Saida
    El Jazouli, Abdelaziz
    Lachgar, E. T. A.
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2009, 65 : S199 - S199
12345