CHEMISTRY IN SUPERACIDS .8. SUPERACID-CATALYZED CARBONYLATION OF METHANE, METHYL HALIDES, METHYL-ALCOHOL, AND DIMETHYL ETHER TO METHYL ACETATE AND ACETIC-ACID

被引：45

作者：

BAGNO, A ^{[1
]}

BUKALA, J ^{[1
]}

OLAH, GA ^{[1
]}

机构：

[1] UNIV SO CALIF,DONALD P & KATHERINE B LOKER HYDROCARBON RES INST,UNIV PK,LOS ANGELES,CA 90089

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 14期

关键词：

D O I：

10.1021/jo00301a015

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Superacid-catalyzed (BF3, BF3-H20, HF-BF3, and CF3S03H) carbonylation of methane and its substituted derivatives (particularly, methyl alcohol and dimethyl ether) gave acetic acid and methyl acetate. HF-BF3 was found to be the most effective catalyst, giving nearly complete conversion of methyl alcohol or dimethyl ether. CF3SO3H led to lower yields and also to the formation of methyl trifluoromethanesulfonate. Possible reaction pathways and mechanisms are discussed on the basis of experimental results. Contrasted with Rh-catalyzed carbonylation of methyl alcohol, the superacid-catalyzed reaction does not necessitate expensive catalyst and conditions necessary with sensitive organometallic catalyst systems. © 1990, American Chemical Society. All rights reserved.

引用

页码：4284 / 4289

页数：6

共 11 条

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[2] Selective carbonylation of dimethyl ether to methyl acetate catalyzed by acidic zeolites
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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (10) : 1617 - 1620
[3] Acid-modified mordenite for enhancing methyl acetate production from dimethyl ether carbonylation
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[4] ON THE RHODIUM-CATALYZED FORMATION OF ACETIC-ACID FROM METHYL FORMATE - COMPARISON WITH THE RHODIUM-CATALYZED FORMATION OF ACETIC-ACID BY DIRECT CARBONYLATION OF METHANOL
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JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1995, 95 (01) : 45 - 52
[5] PROPERTIES OF MIXED ADSORBED MONOLAYER FORMED AT THE SURFACE OF ACETIC-ACID METHYL-ALCOHOL AQUEOUS-SOLUTIONS
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COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1994, 83 (02) : 151 - 159
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OLAH, GA
BUKALA, J
JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (14): : 4293 - 4297
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